Oxidation of bismuth-tungsten bronzes |
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Authors: | DA Jefferson MK Uppal David J Smith |
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Institution: | Department of Physical Chemistry, Lensfield Road, Cambridge CB2 1EP. United Kingdom;High Resolution Electron Microscope, University of Cambridge, Free School Lane, Cambridge CB2 3RQ, United Kingdom |
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Abstract: | The oxidation of bismuth-tungsten bronzes at 600 and 950°C has been studied using high-resolution electron microscopy at 200 and 500 kV. At the lower temperature, a topotactic transformation to lamellae of Bi2WO6 in a WO3 matrix was observed but at higher temperature larger crystals were produced, primarily of Bi2W2O9 but with some disordered intergrowths. |
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Keywords: | To whom all correspondence should be addressed |
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