| DBBD及其Cu(Ⅰ)配位聚合物[CuI(DBBD)2]n的合成 |
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| 引用本文： | 瞿志荣. DBBD及其Cu(Ⅰ)配位聚合物[CuI(DBBD)2]n的合成[J]. 无机化学学报, 2007, 23(5) |
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| 作者姓名： | 瞿志荣 |
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| 作者单位： | 东南大学化学化工学院,南京,210096 |
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| 摘 要： |
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| 关 键 词： | 一价铜 配位聚合物 合成 晶体结构 |
Synthesis of DBBD and Copper(Ⅰ) Coordination Polymer [CuI(DBBD)2]n |
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| QU Zhi-Rong. Synthesis of DBBD and Copper(Ⅰ) Coordination Polymer [CuI(DBBD)2]n[J]. Chinese Journal of Inorganic Chemistry, 2007, 23(5) |
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| Authors: | QU Zhi-Rong |
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| Abstract: | In this article we report the synthesis of (R,S)-4,4'-biquinoline-6,6'-dimethyl-3,3'-dicarboxylate (DBBD)(1) and the formation of copper(Ⅰ) coordination polymer [CuI(DBBD)2]n (2) by inducing a bidentate organic ligand (DBBD). The crystal 1 belongs to monoclinic system with space group P21, and a=0.881 30(19) nm, b=1.9660(6)system with space group Fmm2, and a=2.04441 (17) nm, b=1.543 06 (13) nm, c=1.65245 (13) nm, V=5.2129(7) |
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| Keywords: | Cu(Ⅰ) coordination polymer synthesis crystal structure |
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