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| Hydrothermal Synthesis and Structural Characterization of the Cage-based Arsenic-Vanadium Microporous Material: [As_2V~(IV)_8V~V_2O_(26)]·8H_2O | |
| 作者姓名： | Shou Tian ZHENG1 Yan Qiong SUN1 Guo Yu YANG1 2 * 1Coordination and Hydrothermal Chemisrty Group State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 2State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210093 |
| 作者单位： | Shou Tian ZHENG1，Yan Qiong SUN1，Guo Yu YANG1，2 * 1Coordination and Hydrothermal Chemisrty Group，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou 350002 2State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing 210093 |
| 摘 要： | Interest in polyoxometalates is expanding rapidly due to the enormous variety of structure topologies leading to interesting and unexpected properties in such diverse field as catalysis, materials science and medicine1-4. Frameworks constructed from square pyramidal, octahedral, tetrahedral units are well documented in the solid-state phases of the V/O/P system5. For the heteropolyanions class of clusters, the V/O/As system has been extensively studied, but the linking of arsenic-vanadium … |
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