35Cl NQR of cyclic α-chlorovinyl ethers and orbital interactions in O-C-Cl triad |
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| Authors: | A. A. Bredikhin A. I. Andreeva I. A. Safin A. N. Vereshchagin |
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| Affiliation: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR;(2) Physicotechnical Institute, Kazan Branch, Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions In a series of compounds with fragments OCsp3-Cl or OCsp2-Cl, O=CCl, the relationships observed in the changes in35Cl NQR frequencies are explained by geometric and energy characteristics of the orbitals n(0) and *(CCl).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2204–2207, October, 1985. |
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