Thermodynamic parameters for the molecular inclusion reactions of some azo compounds with α-cyclodextrin |
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| Authors: | Noboru Yoshida Akitoshi Seiyama Masatoshi Fujimoto |
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| Affiliation: | (1) Department of Chemistry Faculty of Science, Hokkaido University, 060 Sapporo, Japan |
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| Abstract: | Molecular inclusion reactions of some azo compounds with  -cyclodextrin were studied in aqueous solution by means of a stopped-flow method. The forward rate constants for the inclusion reactions were found to be in the order of 10–104 mol–1 dm3 s–1. The thermodynamic activation parameters were also determined firstly in -cyclodextrin system. |
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