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开放光程TDLAS系统对北京城区NH3浓度的连续检测
引用本文:陈东,刘文清,张玉钧,刘建国,王晓梅,阚瑞峰,王敏. 开放光程TDLAS系统对北京城区NH3浓度的连续检测[J]. 光学技术, 2007, 33(2): 311-314
作者姓名:陈东  刘文清  张玉钧  刘建国  王晓梅  阚瑞峰  王敏
作者单位:中国科学院安徽光学精密机械研究所,环境光学与技术重点实验室,合肥,230031;中国科学院安徽光学精密机械研究所,环境光学与技术重点实验室,合肥,230031;中国科学院安徽光学精密机械研究所,环境光学与技术重点实验室,合肥,230031;中国科学院安徽光学精密机械研究所,环境光学与技术重点实验室,合肥,230031;中国科学院安徽光学精密机械研究所,环境光学与技术重点实验室,合肥,230031;中国科学院安徽光学精密机械研究所,环境光学与技术重点实验室,合肥,230031;中国科学院安徽光学精密机械研究所,环境光学与技术重点实验室,合肥,230031
基金项目:国家863计划资助项目(2005AA641010),国家自然科学基金资助项目(10274080)
摘    要:氨气是大气酸性成分的主要中和剂,是影响区域空气质量、大气能见度以及酸性沉降的重要因素。研制了基于开放光程近红外可调谐半导体激光吸收光谱(Tunable diode laser absorption spectroscopy,TDLAS)技术的大气NH3浓度连续监测系统,并对北京城区大气NH3浓度进行了两个星期的连续检测。检测结果表明,北京城区大气具有较高的NH3浓度,且具有明显的日变化周期特征,基本特点是白天浓度低,夜晚浓度高且变化相对平缓。相关性研究表明,非农业排放源,特别是城市交通的机动车尾气排放是北京城区大气NH3的主要来源。

关 键 词:激光技术  可调谐半导体激光吸收光谱(TDLAS)  氨气
文章编号:1002-1582(2007)02-0311-04
收稿时间:2006-03-06
修稿时间:2006-03-06

Successive measurement of atmospheric ammonia in urban area of Beijing using open-path TDLAS system
CHEN Dong,LIU Wen-qing,ZHANG Yu-jun,LIU Jian-guo,WAN Xiao-mei,KAN Rui-feng,WANG Min. Successive measurement of atmospheric ammonia in urban area of Beijing using open-path TDLAS system[J]. Optical Technique, 2007, 33(2): 311-314
Authors:CHEN Dong  LIU Wen-qing  ZHANG Yu-jun  LIU Jian-guo  WAN Xiao-mei  KAN Rui-feng  WANG Min
Abstract:Gaseous ammonia is the most important neutralization agent of atmospheric acids,it plays an important role in regional air quality,atmospheric visibility,and acid deposition.An open-path near infrared tunable diode laser absorption spectroscopy(TDLAS) based on atmospheric NH3 successive monitor system has been developed,and has been used to achieve successive measurements of atmospheric NH3 concentration in the urban area of Beijing for two weeks.The experimental results show that the atmospheric NH3 concentration in the urban area of Beijing is high,and has a very clear diurnal variation cycle,the general characteristics of diurnal variation are the lowest value in the daytime and the highest value at night.Correlation studies show that the nonagricultural emission is the main contribution of atmosphere NH3 in the urban area of Beijing,especially the emissions of city transportation vehicles
Keywords:laser techniques  tunable diode laser absorption spectroscopy(TDLAS)  ammonia
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