Abstract: | The He (Iα) photoelectron spectra of the four unsaturated oxides 3,4-dihydropyran ( 6 ), γ-pyran ( 7 ), 2, 3-dihydro-1, 4-dioxin ( 9 ) and 1, 4-dioxin ( 10 ) are reported and analysed. Band assignments are based on ab-initio calculations, using the STO-3G basis set. The proposed orbital sequences (with reference to the coordinate systems given in Table 1) are, for the top three orbitals: 6 , π, nσ, nπ; 7 , 3b1(π), 1a2(π), 11a1(σ); 9 , 11b(π), 12a(σ), 11a(π); 10 , 2b3u(π), 1b1g(π), 6ag(σ). Finally the (almost) localized π-orbitals have been computed by the Foster-Boys localization procedure. |