Einfluss der Lipophilie von 3, 6-Dioxakorksäurediamiden auf ihr Verhalten als Ionophore |
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| Authors: | Ren Bissig,Urs Oesch,Ern Pretsch,Werner E. Morf,Wilhelm Simon |
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| Affiliation: | René Bissig,Urs Oesch,Ernö Pretsch,Werner E. Morf,Wilhelm Simon |
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| Abstract: | Influence of the lipophilicity of 3,6-dioxaoctanedioic diamides on their ion carrier properties A series of lipophilic 3,6-dioxaoctanedioic diamides (potential ionophores for Ca2+) have been prepared. With increasing lipophilicity the ionophoric behavior of these ligands vanishes. This loss is shown to be due to kinetic limitations in the exchange reactions between aqueous phase and membrane phase. |
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