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Photoinduced fragmentation and rearrangement of phenyl substituted epoxyethylphosphonates |
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| Authors: | Claibourne E Griffin Ekkehard Kraas Hirofumi Terasawa Gary W Griffin David C Lankin |
| Abstract: | An alternative source to phosphonocarbenes is described using phosphorus substituted oxiranes as precursors which compliments the conventional diazo route to these transient species. The results are in accord with previous theories advanced to rationalize the mode of photocyclo-elimination of a variety of other unsymmetrically substituted oxiranes. |
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