Hydrocarbonylation of 2,2-dimethoxypropane catalysed by rhodium and cobalt complexes |
| |
| Affiliation: | 1. Department of Chemistry, College of Science, University of Sulaimani, Qliasan St, 46002, Sulaimani City, Kurdistan Region, Iraq;2. Center for Biomedical Analysis, Department of Chemistry, College of Science, University of Sulaimani, Qliasan St, 46002, Sulaimani City, Kurdistan Region, Iraq;1. Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Southwest Jiaotong University, Chengdu, 610031, China;2. School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, 610031, China;3. Leibniz-Institute of Polymer Research Dresden, Max Bergmann Center of Biomaterials Dresden, Hohe Strasse 6, 01069, Dresden, Germany;4. School of Medicine, University of Electronic Science and Technology of China, Chengdu, 611731, China;1. Key Laboratory for Green Chemical Technology of Ministry of Education, R&D Center for Petrochemical Technology, Tianjin University, Tianjin 300072, China;2. Zhejiang Institute of Tianjin University, Ningbo, Zhejiang 315201, China;3. State Key Laboratory of Engines, Tianjin University, Tianjin 300072, China;1. CSIRO, Energy, Queensland Centre for Advanced Technologies, 1 Technology Court, Pullenvale, QLD 4069, Australia;2. CSIRO, Manufacturing, Private Bag 10, Clayton South, VIC 3169, Australia;1. Department of Chemistry, College of Science, University of Zakho, Duhok City, Kurdistan Region, Iraq;2. Center for Biomedical Analysis, Department of Chemistry, College of Science, University of Sulaimani, Qliasan St, 46002, Sulaimani City, Kurdistan Region, Iraq |
| |
| Abstract: | The hydrocarbonylation of 2,2-dimethoxypropane (DMP) with synthesis gas catalysed by rhodium and cobalt complexes has been studied. The major product is either diethyl ether or acetaldehyde dimethylacetal (ADMA), arising from the homologation of the methoxy groups of the ketal. The operating conditions and ligand environment of the metal have been optimized to reduce the secondary aldolization reactions. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
