Chiral magnetic metal-organic frameworks of Mn(II) with achiral tetrazolate-based ligands by spontaneous resolution |
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| Authors: | Tong Xiao-Lan Hu Tong-Liang Zhao Jiong-Peng Wang Yue-Kui Zhang Hui Bu Xian-He |
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| Institution: | Department of Chemistry, and Tianjin Key Lab on Metal and Molecule-based Material Chemistry, Nankai University, Tianjin 300071, China. |
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| Abstract: | The enantiomers of complex 1 (1a and 1b) have been obtained by spontaneous resolution upon crystallization in the absence of a chiral source. The enantiomeric nature of 1a and 1b was confirmed by circular dichroism (CD) spectra and theoretical investigation. |
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