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New fluorine-containing ethers
Authors:K N Makarov  T N Abroskina  Yu A Cheburkov  I L Knunyants
Institution:1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
Abstract:
1.  The cesium chloride adducts with perfluoroacetone, 1-methyl-2-oxaperfluoroenanthyl fluoride, and perfluoroisobutylene react smoothly with symmetrical dichlorodimethyl ether, replacing both chlorine atoms, with the formation of the corresponding ethers.
2.  The interaction ofagr,agr-dihydroperfluoroamyl alcoholate with symmetrical dichlorodimethyl ether leads to the replacement of both chlorine atoms, with the formation of the corresponding ether.
3.  The reaction of perfluoro-t-butylanion with tris(chloromethyl)amine leads to tris-(1,1-dihydro-perfluoroneopentyl) amine.
4.  Perfluoro-t-butylanion replaces only one chlorine atom in the molecule of unsymmetrical di-chlorodimethyl ether, formingagr-chloro-agr -perfluoro-t-butyldimethyl ether.
Keywords:
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