New fluorine-containing ethers |
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Authors: | K N Makarov T N Abroskina Yu A Cheburkov I L Knunyants |
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Institution: | 1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
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Abstract: | 1. |
The cesium chloride adducts with perfluoroacetone, 1-methyl-2-oxaperfluoroenanthyl fluoride, and perfluoroisobutylene react smoothly with symmetrical dichlorodimethyl ether, replacing both chlorine atoms, with the formation of the corresponding ethers.
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The interaction of,-dihydroperfluoroamyl alcoholate with symmetrical dichlorodimethyl ether leads to the replacement of both chlorine atoms, with the formation of the corresponding ether.
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The reaction of perfluoro-t-butylanion with tris(chloromethyl)amine leads to tris-(1,1-dihydro-perfluoroneopentyl) amine.
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Perfluoro-t-butylanion replaces only one chlorine atom in the molecule of unsymmetrical di-chlorodimethyl ether, forming-chloro- -perfluoro-t-butyldimethyl ether.
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