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Phase equilibria study of systems composed of refined babassu oil, lauric acid, ethanol, and water at 303.2 K
Authors:É  rika C. D&rsquo  Anton Reipert,Christianne E.C. Rodrigues,Antonio J.A. Meirelles
Affiliation:aEXTRAE, Department of Food Engineering (DEA-FEA), University of Campinas (UNICAMP), P.O. Box 6121, Zip Code 13083-862, Campinas, SP, Brazil;bLES, Department of Food Engineering (ZEA-FZEA), University of São Paulo (USP), P.O. Box 23, Zip Code 13635-900, Pirassununga, SP, Brazil
Abstract:Deacidification of vegetable oils can be performed using liquid–liquid extraction as an alternative method to the classical chemical and physical refining processes. This paper reports experimental data for systems containing refined babassu oil, lauric acid, ethanol, and water at 303.2 K with different water mass fractions in the alcoholic solvent (0, 0.0557, 0.1045, 0.2029, and 0.2972). The dilution of solvent with water reduced the distribution coefficient values, which indicates a reduction in the loss of neutral oil. The experimental data were used to adjust the NRTL equation parameters. The global deviation between the observed and the estimated compositions was 0.0085, indicating that the model can accurately predict the behavior of the compounds at different levels of solvent hydration.
Keywords:Liquid&ndash  liquid extraction   Liquid&ndash  liquid equilibrium   Experimental data   Deacidification   Solvent extraction   NRTL
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