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Thermodynamic properties of biofuels: Heat capacities of binary mixtures containing ethanol and hydrocarbons up to 20 MPa and the pure compounds using a new flow calorimeter
Authors:David Vega-Maza,José   J. Segovia,M. Carmen Martí  n,Rosa M. Villamañ  á  n,Miguel A. Villamañ  á  n
Affiliation:Research Group TERMOCAL, Thermodynamics and Calibration, Department of Energy, University of Valladolid, Paseo del Cauce 59, E-47011 Valladolid, Spain
Abstract:Heat capacities are of great significance in the design of new processes and the improvement of existing ones in R&D in production plants as well as the adaptation of new products, in this case, biofuels to their use in a variety of engines and technical devices. An automated flow calorimeter has been developed for the accurate measurement of isobaric heat capacities for pure compounds and mixtures over the range (250 to 400) K and (0 to 20) MPa. In this paper, isobaric heat capacities for heptane, ethanol and the binary mixtures of ethanol with heptane and toluene are reported.
Keywords:Isobaric heat capacity   Ethanol   High pressure   Heptane   Toluene
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