Electroreduction of dinitrogen in a Ti(III)?Mo(III)-guanidine system |
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| Authors: | S I Kulakovskaya L P Vasilieva and O N Efimov |
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| Institution: | (1) Institute of Chemical Physics, Chernogolovka, Moscow, USSR |
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| Abstract: | Dinitrogen reduction on a mercury cathode has been studied in an alkaline methanol solution with guanidine buffer (pK=13.6) in the presence of homogeneous catalysts (alkoxy complexes of Mo(III) and Ti(III). As is found, dinitrogen electroreduction occurs on the electrode surface. The reaction rate is determined by the rate of electron transfer.
                   (pK=13,6)       - Ti(III) Mo(III).  , .     .
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