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Prompt-gamma activation analysis using thek 0 approach
Authors:G L Molnár  Zs Révay  R L Paul  R M Lindstrom
Institution:(1) Department of Nuclear Research, Institute of Isotopes, P.O.Box 77, H-1525 Budapest, Hungary;(2) Analytical Chemistry Division, National Institute of Standards and Technology, 20899 Gaithersburg, MD, USA
Abstract:Applying thek 0 standardization method to prompt-gamma activation analysis (PGAA) offers similar benefits as in instrumental neutron activation analysis. It has been demonstrated that under constant flux conditionsk 0-factors obtained by normalizing to a titanium comparator, measured separately, yield consistent analytical sensitivity ratios. The ratio method has been generalized by using stoichiometric compounds for the determination ofk 0-factors. Since chlorine forms compounds with essentially everyelement and it also serves as a detector efficiency standard,k 0 values have been determined relative to chlorine as an internal standard for several analytically important elements in two reactor facilities: the thermal guided beam at the BRR in Budapest and the cold-neutron beams at the NBSR at NIST.
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