Interaction of cyanocobalamin with sulfur-containing reducing agents in aqueous solutions |
| |
| Authors: | D. S. Salnikov I. A. Dereven’kov E. N. Artyushina S. V. Makarov |
| |
| Affiliation: | 1. Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia
|
| |
| Abstract: | The kinetics and mechanism of cyanocobalamin reduction by sodium hydroxymethanesulfinate and dithionite in alkaline media are studied. It is established that the character of the rate-determining step depends on the concentration of the reducing agents: when they are in excess, it is a step of elimination of cyanocobalamin, at lower concentrations of reducing agents a rate-determining is a step of their addition to cobalamin. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
