Studies of the isotopomer determination method for the hydrogen-deuterium exchange of methane. Introduction of methane by a pulse in a deuterium stream at high temperature |
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| Authors: | Tsutomu Osawa Kouhei Sugimoto Maki Miyamoto and Osamu Takayasu |
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| Institution: | (1) Faculty of Science, University of Toyama, Gofuku, Toyama 930-8555, Japan |
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| Abstract: | The H/D exchange reactions of methane in a deuterium stream using a fixed bed flow reactor were studied. In order to precisely
determine the ratio of the exchanged products by a quadrupole mass spectrometry, a new method of corrections for the fragmentation
peaks was developed. |
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| Keywords: | Hydrogen-deuterium exchange methane fragmentation |
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