| Structure and properties of Ni(110) surface coadsorbing chlorine and oxygen |
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| 引用本文： | 庄叔贤,季明荣,吴建新,屠兢,方文秀,俞爽英,Klaus Wandelt. Structure and properties of Ni(110) surface coadsorbing chlorine and oxygen[J]. 中国科学B辑(英文版), 1996, 0(5) |
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| 作者姓名： | 庄叔贤 季明荣 吴建新 屠兢 方文秀 俞爽英 Klaus Wandelt |
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| 作者单位： | Department of Chemical Physics and Structure Research Laboratory，University of Science and Technologyof China，Hefei 230026，China，Department of Chemical Physics and Structure Research Laboratory，University of Science and Technologyof China，Hefei 230026，China，Department of Chemical Physics and Structure Research Laboratory，University of Science and Technologyof China，Hefei 230026，China，Department of Chemical Physics and Structure Research Laboratory，University of Science and Technologyof China，Hefei 230026，China，Department of Chemical Physics and Structure Research Laboratory，University of Science and Technologyof China，Hefei 230026，China，Department of Chemical Physics and Structure Research Laboratory，University of Science and Technologyof China，Hefei 230026，China，Institute of Physical Chemistry，University of Bonn，Wegelerstr. 12，D-53115 Bonn，F. R. Germany |
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| 基金项目： | Project supported by the National Natural Science Foundation of China |
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| 摘 要： | The coadsorption of chlorine with oxygen on Ni(110) surface has been investigated by XPS, UPS, AES and work function measurements. The chlorine preadsorption drastically inhibits the further uptake of oxygen. On the contrary, precovered oxygen has hardly any influence on the additional adsorption of chlorine due to the incorporation of precovered oxygen into the subsurface driven by the chlorine coadsorption. ARXPS measurements provide the evidence for this coadsorption model. The thermal desorption of chlorine and oxygen from the coadsorption surface is very similar to that of both individual adsorbates under the same heating conditions, but the desorption temperature of both the adsorbates apparently decreases on the coadsorption surface. The coadsorption and thermodesorption mechanisms are also discussed in detail.
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Structure and properties of Ni(110) surface coadsorbing chlorine and oxygen |
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| ZHUANG Shuxian JI Mingrong WU JianxinTU Jing FANG Wenxiu YU Shuangying. Structure and properties of Ni(110) surface coadsorbing chlorine and oxygen[J]. Science in China(Chemistry), 1996, 0(5) |
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| Authors: | ZHUANG Shuxian JI Mingrong WU JianxinTU Jing FANG Wenxiu YU Shuangying |
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| Abstract: | The coadsorption of chlorine with oxygen on Ni(110) surface has been investigated by XPS, UPS, AES and work function measurements. The chlorine preadsorption drastically inhibits the further uptake of oxygen. On the contrary, precovered oxygen has hardly any influence on the additional adsorption of chlorine due to the incorporation of precovered oxygen into the subsurface driven by the chlorine coadsorption. ARXPS measurements provide the evidence for this coadsorption model. The thermal desorption of chlorine and oxygen from the coadsorption surface is very similar to that of both individual adsorbates under the same heating conditions, but the desorption temperature of both the adsorbates apparently decreases on the coadsorption surface. The coadsorption and thermodesorption mechanisms are also discussed in detail. |
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| Keywords: | coadsorption of chlorine with oxygen Ni(110) surface photoelectron spectroscopy. |
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