Catalytic oxidation of hydrogen in solutions of metal complexes |
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| Authors: | G. I. Golodets and N. I. Ilchenko |
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| Affiliation: | (1) Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev, USSR |
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| Abstract: | The kinetics of H2 oxidation at 25°C in solutions of Pd-histidine complexes has been studied and a reaction mechanism suggested for the explanation of the experimental data. In terms of this mechanism, the correlation between the activities of homogeneous catalysts and reactant-catalyst bond energies are considered. The oxygen-catalyst bond energy proves to be a determining factor similarly as in heterogeneous catalytic oxidation.
                  25°C   Pd  ,    ;      .
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