Iron-catalyzed electrochemical allylation of carbonyl compounds by allylic acetates |
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Authors: | Durandetti Muriel Meignein Clotilde Périchon Jacques |
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Institution: | Laboratoire d'Electrochimie, Catalyse et Synthèse Organique, UMR 7582 CNRS, 2 rue Henri-Dunant, 94320 Thiais, France. durandetti@glvt-cnrs.fr |
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Abstract: | Homoallylic alcohols were synthesized from aldehydes or ketones and allylic acetates, using an electrochemical process catalyzed by iron complexes. We first studied the reactivity of allyl acetate, using N,N-dimethylformamide (DMF) or acetonitrile (AN) as solvent, FeBr(2) as catalyst, and Fe as the sacrificial anode. Then we tested the regioreactivity of crotyl acetate and other allylic derivatives. |
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