Design of amphiphilic poly(vinylidene fluoride-co-hexafluoropropylene)-based gel electrolytes for high-performance lithium-ion batteries |
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| Authors: | Yongfen?Tong,Mingming?Que,Shan?Su,Lie?Chen author-information" > author-information__contact u-icon-before" > mailto:chenlienc@.com" title=" chenlienc@.com" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author |
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| Affiliation: | 1.School of Environmental and Chemical Engineering,Nanchang Hangkong University,Nanchang,China;2.College of Chemistry,Nanchang University,Nanchang,China;3.Jiangxi Nuclear Industry Machinery Research Institute,Nanchang,China |
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| Abstract: | Gel polymer electrolytes (GPE) based on electrospun polymer membranes, poly(vinylidene fluoride-co-hexafluoropropylene), grafted poly(poly(ethylene glycol) methyl ether methacrylate) (PVDF-HFP-g-PPEGMA), and poly(vinylidene difluoride-co-hexafluoropropylene) (PVDF-HFP) are prepared for lithium ion batteries by incorporating with 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (BMITFSI). The uniform porosity and the compatibility of blend electrospun membranes avoiding the pore blocking are beneficial to enhance the electrolyte uptakes. The GPE based on the fibrous PVDF-HFP-g-PPEGMA/PVDF-HFP activated with 1 M LiTFSI (BMITFSI) show a maximum ionic conductivity of 2.3 × 10?3 S cm?1 at room temperature and electrochemical stability of up to 5.2 V. The Li/GPE/LiFePO4 cells with GPE based on PVDF-HFP-g-PPEGMA/PVDF-HFP blend electrospun membrane deliver specific capacities of 163, 141, and 125 mAh g?1 at 0.1, 0.5, and 1C rates, respectively, and remains well after 50 cycles for each rate. Therefore, the novel GPE have been demonstrated to be suitable for lithium-ion battery applications. |
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