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Electron Transfer Studies of Ruthenium(II) Complexes with Biologically Important Phenolic Acids and Tyrosine |
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| Authors: | Angusamy?Rajeswari Arumugam?Ramdass Paulpandian?Muthu Mareeswaran |
| Institution: | 1.School of Chemistry,Madurai Kamaraj University,Madurai,India;2.Department of Chemistry,Fatima College,Madurai,India;3.Research Department of Chemistry,Aditanar College of Arts and Science,Tiruchendur,India;4.Department of Industrial Chemistry,Alagappa University,Karaikudi,India;5.Postgraduate and Research Department of Chemistry,Vivekananda College,Madurai,India |
| Abstract: | The ruthenium(II) complexes having 2,2′-bipyridine and phenanthroline derivatives are synthesized and characterized. The photophysical properties of these complexes at pH 12.5 are studied. The electron transfer reaction of biologically important phenolic acids and tyrosine are studied using absorption, emission and transient absorption spectral techniques. Semiclassical theory is applied to calculate the rate of electron transfer between ruthenium(II) complexes and biologically important phenolic acids. |
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