| THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION |
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| 作者姓名： | 丘坤元 张璋华 冯新德 |
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| 作者单位： | Department of Chemistry，Peking University，Beijing 100871，Department of Chemistry，Peking University，Beijing 100871，Department of Chemistry，Peking University，Beijing 100871 |
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| 基金项目： | The project supported by the National Natural Science Foundation of China |
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| 摘 要： | The effects of N-2-hydroxyethyl-N-methyl-p-toluidine (HMT) on MMA polymerization using organic peroxide as an initiator and on AN photoinduced polymerization have been investigated respectively. The kinetics of polymerization and the overall activation energy of polymerization were determined. Based on kinetics study and the end group analysis of the polymer obtained by UV spectrum method, the initiation mechanism is proposed.
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| 收稿时间： | 1992-01-06 |
THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION |
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| QIU Kunyuan,ZHANG Zhanghua,FENG Xinde.THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION[J].Chinese Journal of Polymer Science,1992,0(3):250-257. |
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| Authors: | QIU Kunyuan ZHANG Zhanghua FENG Xinde |
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| Institution: | Department of Chemistry; Peking University; Beijing |
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| Abstract: | The effects of N-2-hydroxyethyl-N-methyl-p-toluidine (HMT) on MMA polymerization using organic peroxide as an initiator and on AN photoinduced polymerization have been investigated respectively. The kinetics of polymerization and the overall activation energy of polymerization were determined. Based on kinetics study and the end group analysis of the polymer obtained by UV spectrum method, the initiation mechanism is proposed. |
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