meso-Aryl triphyrin(2.1.1) |
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| Authors: | Anju K S Ramakrishnan S Srinivasan A |
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| Institution: | Photosciences and Photonics Section, Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (CSIR), Thiruvananthapuram-695 019, Kerala, India. |
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| Abstract: | Synthesis, spectral, and single-crystal X-ray structural analysis of meso-aryl triphyrin(2.1.1) featuring three pyrrole rings and four meso-aryl rings are described. The title compound represents the first example of a ring-contractedmeso-aryl β-unsubstituted free-base triphyrin containing only pyrrole rings reported to date and generates 2-D supramolecular assembly in the solid state. |
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