Solvent effects on the thermodynamics of the formation of hydrogen bonded complexes ofm-cresol III |
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| Authors: | J N Spencer A Grushow T F Ganunis K N Allott S P Kneizys H Willis S Puppala C M Salata A I Zafar B J Stein L C Hahn |
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| Institution: | (1) Department of Chemistry, Franklin and Marshall College, 17604 Lancaster, PA |
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| Abstract: | Thermodynamic parameters for the hydrogen bonded complexes of m-cresol with various bases in the solvent benzene have been determined from calorimetric and spectroscopic data. These data were analyzed by linear solvation energy relationships. When combined with data previously determined for the same complexes in CCl4 and cyclohexane solvents, it is shown that solvent effects on the thermodynamics of hydrogen bond formation are due to solvation of the free m-cresol and base through dipolar and perhaps donor-acceptor interactions. |
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| Keywords: | Hydrogen bonds solvent effects solvatochromic parameters m-cresol |
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