Carbonylation of alkenyl-complexes of ruthenium. The formation of complexes containing,alkene or acyl ligands,and the reaction of the acyl complexes with methanol |
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| Institution: | 1. Institute of Chemistry, Saint Petersburg State University, Universitetskaya nab., 7/9, Saint Petersburg 199034, Russia;2. Department of Chemistry, Saint Petersburg State Forest Technical University, Institutsky per., 5, Saint Petersburg 194021, Russia;1. Aix Marseille Univ, CNRS, Institut de Chimie Radicalaire, UMR 7273, Equipes CT, Avenue Normandie-Niemen, 13397 Marseille Cedex 20, France;2. Aix Marseille Univ, CNRS, Institut de Chimie Radicalaire, UMR 7273, Equipes CMO, Campus Saint-Jérôme, Avenue Normandie-Niemen, 13397 Marseille Cedex 20, France;1. Graduate School of Infection Control Sciences, Kitasato University, 5-9-1 Shirokane, Minato-ku, Tokyo 108-8641, Japan;2. Kitasato Institute for Life Sciences, Kitasato University, 5-9-1 Shirokane, Minato-ku, Tokyo 108-8641, Japan;1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova 28, Moscow, 119991, Russia;2. Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1–3, Moscow, 119991, Russia;3. Plekhanov Russian University of Economics, Stremyannyi Pereulok 36, Moscow, 117997, Russia |
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| Abstract: | The unsaturated complexes RuCl(CO)(RC=CHR′)(PPh3)2 react with CO to give the dicarbonyl complexes RuCl(CO)2(RC=CHR′)(PPh3)2 or the η2-acyl complexes RuCl(CO)(O=CC(R)=CHR′)(PPh3)2, depending on the R and R′ groups. The RuCl(CO)(O=CC(Me)=CHMe)(PPh3)2 complex reacts with methanol to give RuCl(CO)(O2CC(Me)=CHMe)(PPh3)2, which structure has been established by an X-ray diffraction study. |
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