Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand |
| |
| Institution: | 1. Serveis científico-Tècnics, Universitat de les Illes Balears, Crta de Valldemossa Km 7.5, 07122 Palma de Mallorca (Baleares), Spain;2. Departament de Química, Universitat de les Illes Balears, Crta de Valldemossa Km 7.5, 07122 Palma de Mallorca (Baleares), Spain |
| |
| Abstract: | The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2 with an excess of dppa gives Os3(CO)10(dppa)]3 (2) and Os3(CO)10(dppa)]4 (3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
