Binuclear hydroxo-monopentahalophenyl complexes of palladium(II) |
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Affiliation: | 1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi''an, Shaanxi 710069, China;2. School of Materials and Chemical Engineering, Xi''an Technological University, 710021, Xi''an, China;3. Department of Chemical Engineering, University of New Brunswick, Fredericton, New Brunswick, E3B 5A3, Canada |
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Abstract: | The novel binuclear hydroxo-bridged complexes trans-[R(PPh3)Pd(μ-OH)2Pd(PPh3)R] and cis-[R(PPh3)Pd(μ-OH)(μ-pz)Pd(PPh3)R] (R = C6F5 or C6Cl5; pz = pyrazolate) have been prepared, and their structures assigned on the basis of NMR data. |
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