Pd, Pt, and Ru complexes of a pincer bis(amino)amide ligand |
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| Authors: | Ren Peng Vechorkin Oleg Csok Zsolt Salihu Isuf Scopelliti Rosario Hu Xile |
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| Institution: | Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), ISIC-LSCI, BCH 3305, Lausanne, CH 1015, Switzerland. |
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| Abstract: | An improved synthesis of pincer ligand bis(2-dimethylamino)phenyl]amine ((Me)N(2)NH) was reported. Reaction of the Li complex of (Me)N(2)N with suitable Pd, Pt, and Ru precursors gave the corresponding metal complexes. The structures of the Pd, Pt, and Ru complexes were determined. The Ru complex showed activity in catalytic transfer hydrogenation of aryl and alkyl ketones. |
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