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Group 4 metal initiators for the controlled stereoselective polymerization of lactide monomers |
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| Authors: | Buffet Jean-Charles Okuda Jun |
| Affiliation: | Institut für Anorganische Chemie, RWTH Aachen, Landoltweg 1, D-52056 Aachen, Germany. |
| Abstract: | Group 4 metal initiators with a tetradentate bis(phenolato) ligand polymerized meso-lactide efficiently under ring-opening to give syndiotactic polylactide. L-Lactide was converted faster than rac-lactide and meso-lactide. |
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