| 含R_2dtc配体Mo-Cu化合物的动态~(95)Mo NMR |
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| 引用本文： | 曹荣
,雷新建
,谢秀兰
,黄致盈
,洪茂椿
,刘汉钦.含R_2dtc配体Mo-Cu化合物的动态~(95)Mo NMR[J].分析测试学报,1992(5). |
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| 作者姓名： | 曹荣 雷新建 谢秀兰 黄致盈 洪茂椿 刘汉钦 |
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| 作者单位： | 福州结构化学开放实验室，武汉波谱与原子分子物理实验室 |
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| 摘 要： | 本实验利用动态~(95)Mo NMR监测Mo-Cu系列化合物的形成过程,对反应CuCl+NaR_2dtc+MoO_nS,摩尔比3:3:1,溶剂为DMF;R=Et,n=0(Ⅰ);R=Me,n=0(Ⅱ);R=Et,n=2(Ⅲ)进行了研究,观察到具有不同簇骼的多种中间产物的存在及随反应进程相互转化等现象。
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| 关 键 词： | 动态 ~(95)Mo NMR Mo-Cu化合物 |
Dynamic ~(95)Mo NMR Studies Of A Series Mo-Cu-S Complexes Containing R_2dtc Ligands |
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| Cao Rong,Lei Xinjin,Xie Xiulan,Huang Zhiying,Hong Maochun,Liu Hanqin Fuzhou Laboratory of Structural Chemistry and Wuhan Laboratory of Radio Frequencc and Atomic and Molecular Physics,PO Box ,Fujian Fuzhou.Dynamic ~(95)Mo NMR Studies Of A Series Mo-Cu-S Complexes Containing R_2dtc Ligands[J].Journal of Instrumental Analysis,1992(5). |
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| Authors: | Cao Rong Lei Xinjin Xie Xiulan Huang Zhiying Hong Maochun Liu Hanqin Fuzhou Laboratory of Structural Chemistry and Wuhan Laboratory of Radio Frequencc and Atomic and Molecular Physics PO Box Fujian Fuzhou |
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| Institution: | Cao Rong,Lei Xinjin,Xie Xiulan,Huang Zhiying,Hong Maochun,Liu Hanqin Fuzhou Laboratory of Structural Chemistry and Wuhan Laboratory of Radio Frequencc and Atomic and Molecular Physics,350002,PO Box 143,Fujian Fuzhou |
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| Abstract: | In this paper, dynamic ~(9)5Mo NMR technique was used to monitor the reaction of the mix-ture of CuCl, NaS_2CNR_2, and MoO_nS_(4-n)~(2-) (molar ratio 3:3:1)in DMF solution and find the occu-rrences of different products during the reaction procedure and the reaction condition of them,the results show that these reactions give rise to a series of compounds containing Mo_xCu_y(x=1, 2; y=1, 2, 3, 4, 5) and the compounds can be obtained by changing the reaction condi-tions. |
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| Keywords: | Dynamic ~(95)Mo NMR Mo-Cu complex |
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