Hysteretic sorption of light gases by a porous metal-organic framework containing tris(para-carboxylated) triphenylphosphine oxide |
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| Authors: | Humphrey Simon M Oungoulian Shaunt E Yoon Ji Woong Hwang Young Kyu Wise Erica R Chang Jong-San |
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| Institution: | University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW. smh49@cam.ac.uk |
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| Abstract: | The porous metal-organic framework (MOF) PCM-4, based on tris(para-carboxylated) triphenylphosphine oxide, contains atypical, polar organic substituents; the material exhibits a hysteretic sorption of Ar, N2 and O2, and demonstrates the advantage of ligands of this type. |
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