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含典型氟-氢邻近与远程耦合的混合物的核磁共振氢谱示例
引用本文:黄艳,吴江林,庞振国,卢志云.含典型氟-氢邻近与远程耦合的混合物的核磁共振氢谱示例[J].大学化学,2019,34(9):106-109.
作者姓名:黄艳  吴江林  庞振国  卢志云
作者单位:四川大学化学学院,成都,610064;四川大学化学学院,成都,610064;四川大学化学学院,成都,610064;四川大学化学学院,成都,610064
基金项目:国家自然科学基金(21875148);四川大学未来教学项目
摘    要:

关 键 词:核磁共振氢谱    氟-氢耦合  混合物氢谱  多取代苯
收稿时间:2019-02-14

Examples of 1H NMR Spectra of Mixture of Compounds Containing Vicinal and Long-Range Fluorine-Proton Coupling
Yan HUANG,Jianglin WU,Zhenguo PANG,Zhiyun LU.Examples of 1H NMR Spectra of Mixture of Compounds Containing Vicinal and Long-Range Fluorine-Proton Coupling[J].University Chemistry,2019,34(9):106-109.
Authors:Yan HUANG  Jianglin WU  Zhenguo PANG  Zhiyun LU
Institution:
Abstract:Two serials of tetrasubstituted benzene compounds containing fluoro group were designed and synthesized. The other three substitutes are sequentially the para, meta, and ortho to fluoro group. The obtained compounds were all mixtures as confirmed by 1H NMR spectroscopies. The spectra clearly show the proximity and remote interaction between fluorine atom and hydrogen atom. In addition, the two spectra, one showing the overlapping peaks, one not, can be used as the simple and typical example of 1H NMR spectra of mixtures.
Keywords:1H NMR spectroscopy  Fluorine  H-F coupling  1H NMR spectra of mixtures  Multiple substituent benzene  
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