Abstract: | Building blocks have been designed for the non-covalent formation of nanosize assemblies. As non-covalent interactions coordination chemistry and hydrogen bonding have been used. The self-assembly process leads to spherical assemblies with diameters in the range of 100 to 400 nm, with standard deviations in the order of 10–15%. The controlled assembly approach allows a precise controll of size and assemblies with molecular weights up to 10,000 Dalton have been realized. Finally, we have developed a strategy in which hydrogen bonding and coordination chemistry can be applied “orthogonally” |