| 一种测定反应体系压力变化的无汞反应动力学装置 |
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| 引用本文： | 陈荣悌,邓国才,郝金库. 一种测定反应体系压力变化的无汞反应动力学装置[J]. 高等学校化学学报, 1989, 0(3) |
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| 作者姓名： | 陈荣悌 邓国才 郝金库 |
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| 作者单位： | 南开大学化学系(陈荣悌，邓国才)，天津师范大学化学系(郝金库) |
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| 摘 要： | 测量反应体系压力变化的装置已有报道,但本文装置具有操作方便、记数准确等优点。 1 实 验 1.1 实验原理及试剂 详见文献。 1.2 装置及仪器 本文的无汞动力学测量装置用于乙炔氢氯化均相催化反应力学研究,其组装图如图1所示。
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| 关 键 词： | 无汞测压动力学装置 氢氯化反应 乙炔 |
A Kind of Non-Mercury Kinetic Equipment Measuring the Changes in the Pressure of a Reaction System |
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| Chen Rongti,Deng Guocai. A Kind of Non-Mercury Kinetic Equipment Measuring the Changes in the Pressure of a Reaction System[J]. Chemical Research In Chinese Universities, 1989, 0(3) |
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| Authors: | Chen Rongti Deng Guocai |
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| Abstract: | A kind of non-mercury kinetic equipment to measure-the changes in the pressure of a reaction system has been designed. Using this equipment, we have studied the kinetics of the reaction of acetylene hydrochlorination in hydrochloric acid with catalyst HgCl2. The reaction apparent activation energy is 58.2kJ/mol. The results showed that the equipment is very convenient to operating and designed to give the accurate recordings. |
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| Keywords: | Non-mercury kinetic equipment Hydrochlorination Acetylene |
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