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石墨炉原子吸收光谱法测定 北美自然铜矿中的铅
引用本文:汪常明,金正耀,陈彪,尹若春.石墨炉原子吸收光谱法测定 北美自然铜矿中的铅[J].光谱实验室,2011,28(4):2050-2054.
作者姓名:汪常明  金正耀  陈彪  尹若春
作者单位:1. 广西民族大学物理与电子工程学院 南宁市大学东路188号530006
2. 中国科学技术大学科技史与科技考古系 合肥市金寨路96号230026
摘    要:采用石墨炉原子吸收光谱法对北美多个自然铜矿区的55个样品进行了铅含量分析,在制作校准曲线时加入高纯铜溶液以消除基体效应影响,高纯铜及样品加标回收率分别为104.0%和111.0%,表明该方法具有较高的可信度.分析结果表明,北美自然铜中铅含量极低,多数含量低于1μg/g,少数介于1-10μg/g之间.

关 键 词:石墨炉原子吸收光谱法  北美自然铜矿  

Determination of Lead in Native Copper Mine of North America by Graphite Furnace Atomic Absorption Spectrometry
WANG Chang-Ming,JIN Zheng-Yao,CHEN Biao,YIN Ruo-Chun.Determination of Lead in Native Copper Mine of North America by Graphite Furnace Atomic Absorption Spectrometry[J].Chinese Journal of Spectroscopy Laboratory,2011,28(4):2050-2054.
Authors:WANG Chang-Ming  JIN Zheng-Yao  CHEN Biao  YIN Ruo-Chun
Institution:a(Department of Physics and Electricity Engineering,Guangxi University for Nationalities,Nanning 530006,P.R.China)a(Department of History of Sci.& Tech.and Archaeometry,University of Science and Technology of China,Hefei 230026,P.R.China)
Abstract:The lead concentrations in 55 kinds samples from several native copper mine regions in North America were determined by graphite furnace atomic absorption spectrometry(GFAAS).The matrix effect was eliminated by adding the high pure copper to standard solution when standard curve was drew,and the recoveries of high pure copper and native copper samples were 104.0% and 111.0%,respectively,which indicated this method was feasible.The results showed that the lead concentrations of native copper in North America were very low,and the lead contents of most native copper samples were below 1μg/g,while that of the rest were between 1μg/g and 10μg/g.
Keywords:GFAAS  Native Copper Mine of North America  Lead
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