Chemistry of tetracyanoethylene (TCNE): From TCNE to dicyanomethylacetate |
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| Authors: | Qi-Ying Lv Shu-Zhong Zhan Jian-Ge Wang An Ding |
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| Affiliation: | a Department of Chemistry, South China University of Technology, Guangzhou 510640, China
b Department of Chemistry, Luoyang Normal University, Luoyang 471022, China |
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| Abstract: | In the presence of CoCl2 · 6H2O, the reaction of TCNE (tetracyanoethylene) with CH3OH forms a dicyanomethylacetate molecule, which has been obtained as one solvent molecule in one new compound {[Co(bpy)2CN2][(NC)2C-CO2CH3]} · 2H2O (1). It was characterized by IR spectra, UV-Vis spectra, and cyclic voltammogram. Its structure was determined by X-ray crystallography: 1 crystallizes in P2(1)/n with a = 13.3368(17), b = 12.5299(16), c = 16.074(2) Å, α = 90, β = 94.6320(10), γ = 90°, and Z = 2. |
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| Keywords: | N-ligand Crystal structure Co complex Dicyanomethylacetate |
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