Carbocyclic carbene ligands in palladium-catalyzed C-N coupling reactions |
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| Authors: | Christian Taubmann |
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| Affiliation: | Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, D-85747 Garching, Germany |
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| Abstract: | Palladium complexes bearing a cycloheptatrienylidene ligand are powerful precatalysts for C-N coupling reactions. Their catalytic performance is directly compared to analogous 2,3-diphenylcyclopropenylidene complexes. The crystal structure of cis-dibromo(cycloheptatrienylidene)(triphenylphosphane)palladium(II) is presented. |
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| Keywords: | C-N coupling Carbenes Carbocycles Homogeneous catalysis Palladium |
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