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An effective route for the synthesis of cationic palladium complexes of general formula [(Acac)PdLL]A |
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| Authors: | Vitalii S Tkach Dmitrii S Suslov Gennadii V Ratovskii Tuczek Felix |
| Institution: | a Irkutsk State University, K. Marks 1, Irkutsk 664003, Russia b National University of Mongolia, Ulaanbaatar 210646, Mongolia c Institute of Inorganic Chemistry, Christian-Albrecht University, Kiel D-24098, Germany |
| Abstract: | A series of palladium complexes of general formula (Acac)PdL1L2]+A−, where L1, L2 = phosphines and A = BF4, CF3SO3, were synthesized. Preliminary studies show that the complexes are active in selective dimerization of styrene and addition polymerization of norbornene. |
| Keywords: | Boron trifluoride Dimerization Palladium Styrene Norbornene Polymerization |
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