Stepwise unidirectional synthesis of oligo phenylene vinylenes with a series of monomers. Use in plastic solar cells |
| |
Authors: | Jørgensen Mikkel Krebs Frederik C |
| |
Institution: | The Polymer Department, Ris? National Laboratory, P.O. Box 49, DK-4000 Roskilde, Denmark. mikkel.joergensen@risoe.dk |
| |
Abstract: | Four new monomers for directional stepwise synthesis of oligophenylenevinylenes (OPVs) (4-{2-4-(5,5-dimethyl1,3]dioxan-2-yl)-2,5-dipropoxyphenyl]vinyl}benzyl)phosphonic acid diethyl ester, (5-{2-4-(5,5-dimethyl1,3]dioxan-2-yl)-2,5-dipropylphenyl]vinyl}thiophene-2-ylmethyl)phosphonic acid diethyl ester, (5-{2-4-(5,5-dimethyl1,3]dioxan-2-yl)-2,5-dipropoxyphenyl]vinyl}thiophene-2-ylmethyl)phosphonic acid diethyl ester, and (7-{2-4-(5,5-dimethyl1,3]dioxan-2-yl)-2,5-dipropylphenyl]vinyl}benzo1,2,5]thiadiazol-4-ylmethyl)phosphonic acid diethyl ester have been prepared. Trimeric OPVs were then synthesized and tested as active materials in photovoltaic cells. Conversion efficiencies in the range of 0.5-1% were obtained in blends with the soluble C(60) derivative PCBM. A terpyridine end-functionalized trimer and a heterotrimer with a mixed composition of monomers were also prepared. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|