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Quenching excited triplet C60 fullerene by tetracyanoethylene in benzonitrile
Authors:V A Nadtochenko  N N Denisov  I V Rubtsov  A S Lobach  A P Moravsky
Institution:(1) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation
Abstract:Quenching excited triplet3C60 fullerene by tetracyanoethylene (TCNE) in a benzonitrile solution proceeds with a rate constant equal to (4.2±0.3) · 1018 (M · s)–1. The formation of a radical ion pair C60 + · · · TCNE] was observed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1228–1230, July, 1993.
Keywords:excited triplet C60  tetracyanoethylene  rate constant of quenching  laser photolysis
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