Quenching excited triplet C60 fullerene by tetracyanoethylene in benzonitrile |
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Authors: | V A Nadtochenko N N Denisov I V Rubtsov A S Lobach A P Moravsky |
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Institution: | (1) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
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Abstract: | Quenching excited triplet3C60 fullerene by tetracyanoethylene (TCNE) in a benzonitrile solution proceeds with a rate constant equal to (4.2±0.3) · 1018 (M · s)–1. The formation of a radical ion pair C60
+ · · · TCNE–] was observed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1228–1230, July, 1993. |
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Keywords: | excited triplet C60 tetracyanoethylene rate constant of quenching laser photolysis |
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