Trimethylsilylethynyl ketones as surrogates for ethynyl ketones in the double Michael reaction |
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| Authors: | Holeman Derrick S Rasne Ravindra M Grossman Robert B |
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| Institution: | Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055, USA. |
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| Abstract: | Trimethylsilylethynyl ketones can be desilylated in the presence of a tethered carbon diacid and induced to undergo a double Michael reaction in situ. The trimethylsilylethynyl ketones can serve as surrogates of ethynyl ketones that are difficult to prepare or isolate. |
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