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Synthesis and characterization of nitro-Schiff bases derived from 5-nitro-salicylaldehyde and various diamines and their complexes of Co(II)
Abstract:Some neutral tetradentate N2O2 type complexes of Co(II) have been synthesized using Schiff bases formed by condensation of 5-nitro-salicylaldehyde with various diamines in alcohol. The nature of the ligands and complexes was established by spectroscopic techniques. The Schiff bases are bivalent anions with tetradentate ONNO donors derived from phenolic oxygen and azomethine nitrogen. IR and UV-Vis spectral data suggest that all the complexes are square-planar.
Keywords:Synthesis  Nitro-Schiff base  Ligand  Complex  Salicylaldehyde
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