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NOTE: SYNTHESIS OF Cu(II) AND Zn(II) COMPLEXES WITH SCHIFF BASE DERIVATIVES OF 2-ACETYLPYRROLE
Abstract:Abstract

Bis chelate complexes of Cu(II) and Zn(II) were synthesized with methylamine and ethylamine Schiff base derivatiies of 2-acetylpyrrole. Stable complexes were obtained, with the exception of the Cu(II) ethylamine adduct. which slowly hydrolyzed in air to yield a mixed ligand product containing one ethylamine Schiff base and one 2-acetylpyrrole per metal centre. The instability of the bis Cu(II) ethylamine Schiff base complex with respect to stable Cu(II) methylamine and Zn(1I) ethylamine complexes is discussed.
Keywords:Copper  zinc  Schiff base  z-acetylpyrrole  synthesis
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