Syntheses,characterizations and crystal structures of triorganotin(IV) complexes with amine derivatives of 6-amino-1,3,5-triazine-2,4-dithiol |
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Abstract: | Four new triorganotin(IV) complexes: Me3SnL1SnMe3 (1), Ph3SnL1SnPh3 (2), [Me3SnL2] n (3), Ph3SnL2SnPh3 (4) have been synthesized from 6-anilino-1,3,5-triazine-2,4-dithiol (L1H2) and 6-(dibutylamino)-1,3,5-triazine-2,4-dithiol (L2H2). All were characterized by elemental analyses, IR and NMR spectra and X-ray diffraction analyses. Crystal structures show that 1, 2 and 4 are monomers with one ligand coordinated to two triorganotin moieties; complex 3 is a helical chain. Significant C–H ··· π, N–H ··· π interactions and intermolecular hydrogen bonds stabilize these structures. |
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Keywords: | Triorganotin 6-Anilino(or dibutylamino)-1,3,5-triazine-2,4-dithiol Crystal structure |
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