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Synthesis of chiral salen Mn(III) complexes covalently linked to Re(I)-based photosensitizers |
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| Abstract: | Two Mn(III)Re(I) binuclear complexes were prepared as catalyst-photosensitizer models, in which the chiral pyrrolidine salen Mn(III) unit was covalently bonded to an Re(I) bipyridyl carbonyl moiety via a carboxamide linkage. The spectral and electrochemical properties of the Mn(III)Re(I) complexes were studied. |
| Keywords: | Manganese complex Rhenium complex Heterobinuclear complex Chiral salen ligand Pyrrolidine Light-driven catalyst |