Syntheses and crystal structures of two Cu(II) complexes based on a fused heterocycle ligand containing 1,3,4-thiadiazole |
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| Abstract: | By refluxing a mixture of CuCl2 and 3-methyl-6-phenyl-[1,2,4]-triazolo[3,4-b][1,3,4]thiadiazole (TRTZ) with addition of acetic acid and KSCN, respectively, the complexes [Cu(TRTZ)2(OAc)2(H2O)]?·?1.5H2O (1) and [Cu(TRTZ)2(SCN)2(H2O)2]?·?2DMF (2) were obtained. Single-crystal structure of both complexes was determined and their thermal behaviour and IR spectra examined. |
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| Keywords: | 1,3,4-Thiadiazole Copper complex Crystal structure Properties |
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