Supramolecular isomerism of Cu(I) and 3,5-di-2-pyridyl-1,2,4-triazolate via in situ solvothermal ligand reaction: meso-helix and luminescence |
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Abstract: | The sixth supramolecular isomer of Cu(I) and 3,5-di-2-pyridyl-1,2,4-triazolate (2-pytz), Cu2(2-pytz)2] n (1), via in situ solvothermal ligand reaction, has been synthesized and characterized as a rare meso-helical chain. Complex 1 exhibits high thermal stability (until 400°C) confirmed by thermogravimetric analysis and has potential applications as an optical material. This research makes the maximum number of genuine supramolecular isomers with structural characterization, found for coordination polymers, six. |
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Keywords: | Supramolecular isomerism 3 5-Di-2-pyridyl-1 2 4-triazolate Meso-helix Luminescence |
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