| Abstract: | Abstract The ESR spectra of a series of copper(II) alkanoates with the empirical formula Cu2 X 4 (X = heptanoate, octanoate, nonanoate, decanoate, dodecanoate), and their pyridine adducts have been measured over the temperature range 300K to 100K. The spectra of nonadduct copper(II) alkanoates exhibit extreme temperature dependent behavior; the room temperature spectra show a single broad line centered on g ≈ 2.1, however as the temperature is lowered triplet state features appear. The corresponding pyridine adducts give typical triplet state spectra at all temperatures. This temperature behavior can be interpreted in terms of interdimer interactions in copper(II) alkanoates having the polymeric structure. The observed resonance lines are used to calculate the zero-field splitting parameters D and E. The spin Hamiltonian and zero-field splitting parameters are used to estimate the exchange parameter J. The values of /2J/ for the compounds investigated are in the range of 300–400cm?1 and suggest that the copper(II) ions are strongly antiferromagnetically coupled. |
